Articles | Volume 14, issue 1
https://doi.org/10.5194/gi-14-91-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gi-14-91-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 May 2025
Research article |
| 05 May 2025
| 05 May 2025
A multiplexing system for quantifying oxygen fractionation factors in closed chambers
Clémence Paul
CORRESPONDING AUTHOR
Laboratoire des Sciences du Climat et de l'Environnement, LSCE – IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Clément Piel
Ecotron Européen de Montpellier (UAR 3248), Univ Montpellier, Centre National de la Recherche Scientifique (CNRS), Campus Baillarguet, Montferrier-sur-Lez, France
Joana Sauze
Ecotron Européen de Montpellier (UAR 3248), Univ Montpellier, Centre National de la Recherche Scientifique (CNRS), Campus Baillarguet, Montferrier-sur-Lez, France
Olivier Jossoud
Laboratoire des Sciences du Climat et de l'Environnement, LSCE – IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Arnaud Dapoigny
Laboratoire des Sciences du Climat et de l'Environnement, LSCE – IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Daniele Romanini
Laboratoire Interdisciplinaire de Physique, Univ Grenoble Alpes, CNRS/UGA, Saint-Martin-d'Hères, France
Frédéric Prié
Laboratoire des Sciences du Climat et de l'Environnement, LSCE – IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Sébastien Devidal
Ecotron Européen de Montpellier (UAR 3248), Univ Montpellier, Centre National de la Recherche Scientifique (CNRS), Campus Baillarguet, Montferrier-sur-Lez, France
Roxanne Jacob
Laboratoire des Sciences du Climat et de l'Environnement, LSCE – IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Alexandru Milcu
Ecotron Européen de Montpellier (UAR 3248), Univ Montpellier, Centre National de la Recherche Scientifique (CNRS), Campus Baillarguet, Montferrier-sur-Lez, France
CEFE, Univ Montpellier, CNRS, EPHE, IRD, Montpellier, France
Amaëlle Landais
Laboratoire des Sciences du Climat et de l'Environnement, LSCE – IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
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Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
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This paper introduces a new optical gas analyzer based on an optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) technique enabling high-temporal-resolution and high-precision measurements of oxygen isotopes (δ18O) and dioxygen (O2) concentration of atmospheric O2 (respectively 0.06 ‰ and 0.002 % over 10 min integration). The results underscore the good agreement with isotope ratio mass spectrometry measurements and the ability of the instrument to monitor biological processes.
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Inès Ollivier, Thomas Lauwers, Niels Dutrievoz, Cécile Agosta, Mathieu Casado, Elise Fourré, Christophe Genthon, Olivier Jossoud, Frédéric Prié, Hans Christian Steen-Larsen, and Amaëlle Landais
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Oxygen and hydrogen stable isotopes have been extensively used to reconstruct past temperatures, with precipitation representing the input signal of the isotopic records in ice cores. We present a 10-year record of stable isotopes in daily precipitation at Concordia Station: this is the longest record for inland Antarctica and represents a benchmark for quantifying post-depositional processes and improving the paleoclimate interpretation of ice cores.
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Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
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Loïc Martin, Julius Nouet, Arnaud Dapoigny, Gaëlle Barbotin, Fanny Claverie, Edwige Pons-Branchu, Jocelyn Barbarand, Christophe Pécheyran, Norbert Mercier, Fanny Derym, Bernard Gély, and Hélène Valladas
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Carbonate wall deposits of Trou du Renard cave (France) were dated using a multimethod approach: U–Th dating by bulk dissolution of samples and inductively coupled plasma mass spectrometry (ICP-MS), U–Th dating by laser ablation ICP-MS imaging, and radiocarbon dating. The samples were studied to ensure that they give reliable ages. Ages ranging from 187.9 ± 5.3 ka and 1.4 ± 0.1 ka were found. This approach should make it possible to establish more robust chronologies of archaeological caves.
Amaelle Landais, Cécile Agosta, Françoise Vimeux, Olivier Magand, Cyrielle Solis, Alexandre Cauquoin, Niels Dutrievoz, Camille Risi, Christophe Leroy-Dos Santos, Elise Fourré, Olivier Cattani, Olivier Jossoud, Bénédicte Minster, Frédéric Prié, Mathieu Casado, Aurélien Dommergue, Yann Bertrand, and Martin Werner
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We have monitored water vapor isotopes since January 2020 on Amsterdam Island in the Indian Ocean. We show 11 periods associated with abrupt negative excursions of water vapor δ18Ο. Six of these events show a decrease in gaseous elemental mercury, suggesting subsidence of air from a higher altitude. Accurately representing the water isotopic signal during these cold fronts is a real challenge for the atmospheric components of Earth system models equipped with water isotopes.
Christophe Leroy-Dos Santos, Elise Fourré, Cécile Agosta, Mathieu Casado, Alexandre Cauquoin, Martin Werner, Benedicte Minster, Frédéric Prié, Olivier Jossoud, Leila Petit, and Amaëlle Landais
The Cryosphere, 17, 5241–5254, https://doi.org/10.5194/tc-17-5241-2023, https://doi.org/10.5194/tc-17-5241-2023, 2023
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In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023, https://doi.org/10.5194/cp-19-2257-2023, 2023
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A new federative chronology for five deep polar ice cores retrieves 800 000 years of past climate variations with improved accuracy. Precise ice core timescales are key to studying the mechanisms linking changes in the Earth’s orbit to the diverse climatic responses (temperature and atmospheric greenhouse gas concentrations). To construct the chronology, new measurements from the oldest continuous ice core as well as glaciological modeling estimates were combined in a statistical model.
Aymeric P. M. Servettaz, Anaïs J. Orsi, Mark A. J. Curran, Andrew D. Moy, Amaelle Landais, Joseph R. McConnell, Trevor J. Popp, Emmanuel Le Meur, Xavier Faïn, and Jérôme Chappellaz
Clim. Past, 19, 1125–1152, https://doi.org/10.5194/cp-19-1125-2023, https://doi.org/10.5194/cp-19-1125-2023, 2023
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The temperature of the past 2000 years is still poorly known in vast parts of the East Antarctic plateau. In this study, we present temperature reconstructions based on water and gas stable isotopes from the Aurora Basin North ice core. Spatial and temporal significance of each proxy differs, and we can identify some cold periods in the snow temperature up to 2°C cooler in the 1000–1400 CE period, which could not be determined with water isotopes only.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Clémence Paul, Clément Piel, Joana Sauze, Nicolas Pasquier, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Arnaud Dapoigny, Olivier Jossoud, Alexandru Milcu, and Amaëlle Landais
Biogeosciences, 20, 1047–1062, https://doi.org/10.5194/bg-20-1047-2023, https://doi.org/10.5194/bg-20-1047-2023, 2023
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To improve the interpretation of the δ18Oatm and Δ17O of O2 in air bubbles in ice cores, we need to better quantify the oxygen fractionation coefficients associated with biological processes. We performed a simplified analogue of the terrestrial biosphere in a closed chamber. We found a respiration fractionation in agreement with the previous estimates at the microorganism scale, and a terrestrial photosynthetic fractionation was found. This has an impact on the estimation of the Dole effect.
Antoine Grisart, Mathieu Casado, Vasileios Gkinis, Bo Vinther, Philippe Naveau, Mathieu Vrac, Thomas Laepple, Bénédicte Minster, Frederic Prié, Barbara Stenni, Elise Fourré, Hans Christian Steen-Larsen, Jean Jouzel, Martin Werner, Katy Pol, Valérie Masson-Delmotte, Maria Hoerhold, Trevor Popp, and Amaelle Landais
Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, https://doi.org/10.5194/cp-18-2289-2022, 2022
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This paper presents a compilation of high-resolution (11 cm) water isotopic records, including published and new measurements, for the last 800 000 years from the EPICA Dome C ice core, Antarctica. Using this new combined water isotopes (δ18O and δD) dataset, we study the variability and possible influence of diffusion at the multi-decadal to multi-centennial scale. We observe a stronger variability at the onset of the interglacial interval corresponding to a warm period.
Clément Outrequin, Anne Alexandre, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Amaelle Landais, Martine Couapel, Jean-Charles Mazur, Christophe Peugeot, Monique Pierre, Frédéric Prié, Jacques Roy, Corinne Sonzogni, and Claudia Voigt
Clim. Past, 17, 1881–1902, https://doi.org/10.5194/cp-17-1881-2021, https://doi.org/10.5194/cp-17-1881-2021, 2021
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Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Christophe Leroy-Dos Santos, Mathieu Casado, Frédéric Prié, Olivier Jossoud, Erik Kerstel, Morgane Farradèche, Samir Kassi, Elise Fourré, and Amaëlle Landais
Atmos. Meas. Tech., 14, 2907–2918, https://doi.org/10.5194/amt-14-2907-2021, https://doi.org/10.5194/amt-14-2907-2021, 2021
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We developed an instrument that can generate water vapor at low humidity at a very stable level. This instrument was conceived to calibrate water vapor isotopic records obtained in very dry places such as central Antarctica. Here, we provide details on the instrument as well as results obtained for correcting water isotopic records for diurnal variability during a long field season at the Concordia station in East Antarctica.
Axel Fouqueau, Manuela Cirtog, Mathieu Cazaunau, Edouard Pangui, Pascal Zapf, Guillaume Siour, Xavier Landsheere, Guillaume Méjean, Daniele Romanini, and Bénédicte Picquet-Varrault
Atmos. Meas. Tech., 13, 6311–6323, https://doi.org/10.5194/amt-13-6311-2020, https://doi.org/10.5194/amt-13-6311-2020, 2020
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An incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) technique has been developed for the in situ monitoring of NO3 radicals in the CSA simulation chamber at LISA. The optical cavity allows a high sensitivity for NO3 detection up to 6 ppt for an integration time of 10 s. The technique is now fully operational and can be used to determine rate constants for fast reactions involving complex volatile organic compounds (with rate constants up to 10−10 cm3 molecule−1 s−1).
Jinhwa Shin, Christoph Nehrbass-Ahles, Roberto Grilli, Jai Chowdhry Beeman, Frédéric Parrenin, Grégory Teste, Amaelle Landais, Loïc Schmidely, Lucas Silva, Jochen Schmitt, Bernhard Bereiter, Thomas F. Stocker, Hubertus Fischer, and Jérôme Chappellaz
Clim. Past, 16, 2203–2219, https://doi.org/10.5194/cp-16-2203-2020, https://doi.org/10.5194/cp-16-2203-2020, 2020
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We reconstruct atmospheric CO2 from the EPICA Dome C ice core during Marine Isotope Stage 6 (185–135 ka) to understand carbon mechanisms under the different boundary conditions of the climate system. The amplitude of CO2 is highly determined by the Northern Hemisphere stadial duration. Carbon dioxide maxima show different lags with respect to the corresponding abrupt CH4 jumps, the latter reflecting rapid warming in the Northern Hemisphere.
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Short summary
Our study investigated the influence of plant processes on oxygen dynamics, crucial for paleoclimatology. By examining maize respiration and photosynthesis using advanced techniques, we enhanced our understanding of past climates through ice core analysis.
Our study investigated the influence of plant processes on oxygen dynamics, crucial for...
